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  Chemical and physical filters

When exposed to the sun, the skin's defences should be supported by the use of a suitable sunscreen. The most essential constituents of a sunscreen are the filter substances that act as a shield between the sun and the skin.

Basically a distinction is made between physical and chemical UV filters:

Physical UV filters are inorganic substances. The UV radiation reaching their surface is reflected and/or scattered and does not penetrate the skin. These are normally mineral pigments, such as titanium dioxide. An important new development is micronized pigments with a particle size between 10 and 50 nm. When present in a suitable base (cream, lotion), physical light protection is not a cosmetic problem.
Chemical filters are organic, aromatic compounds that can absorb UV radiation. Depending on the wavelength absorbed one differentiates between UVB, UVA, and broadband filters. The absorbed energy is emitted again as thermal radiation.

Not all sunscreens prevent the emigration of the Langerhans` cells and the dispersion of the systemic immunosuppressor interleukin 10 (IL-10). Sunscreens with the UV filter octyl triazone, such as the products in the Eucerin® Sun Sensitive Skin series (Protective Lotion, Protective Cream, Protective Gel, Anti-Ageing Face Cream, Protective Spray, Children's Lotion and Children's Cream), protect the Langerhans` cells of the epidermis from the immunosuppressive effect of UVB radiation, thus guaranteeing an effective immune response.

A medically effective UV protection is attained through a combination of UVA and UVB filters (so-called broadband preparations) with the addition of antioxidants, which reduce the formation of free radicals.
 


According to W. Raab, 1993 Schematic diagram of the effect of chemical UV filters and mineral micropigments.
 
 

 

     
    source: Schauder, S., Göttinger Liste, 1996  
         
UVB protection factor:
The UVB protection factor (SPF) of a sunblock has been determined since 1997 according to the COLIPA standard - a new, standardised, Europe-wide method. The reproducable individual results measured demonstrate the high reliability of the COLIPA method. This standardisation makes it possible for users to obtain a comparable product performance with the same UVB protection factor throughout Europe.


 
         
    Protection factor  
         
  UVA protection factor:
Since the effects of UVA radiation on the skin are long-term, a generally accepted method for determining a UVA protection factor is lacking. For a long time no uniform standard existed. In Australia, the local regulatory authorities developed a photometric process for estimating the reduction of the UVA radiation, which delivers a reproducible, reliable measurement. This standard (Australian standard AS 2604:93), which is the only one of ist kind in the world, requires that sun protection products absorb at least 90%.
     
         
    UVA filtering according to the Australian standard  
         
  Water resistance:
Since water is permeable to UV radiation, a product´s protective capacity in water - and its resistance to water - is of great importance. The test of a product´s resistance to water, however, gives no indication as to how friction affects the water-resistance of a product. Friction, for example from towelling, can remove up to 80% of a sunscreen, leaving it on the towel. After bathing, as well as after the subsequent drying, even a waterproof sunscreen must therefore be reapplied.

A consistent, optimal photoprotection requires the combination of effective, medicinal sun protection products and other measures such as wearing of photoprotective textiles.
     
         
       
         
  Photostability:
UV filters can become unstable through the action of light and the influence of skin enzymes, among other causes. Research has shown that benzophenone, for example, displays a very high level of photostability, while other filter substances such as octyl-dimethyl-PABA degrade more quickly. Because of the trend towards using a high protection factor in sunscreens, substances should be used that are also UV-stable.
     
         
       
         
 
SUMMARY:

To protect the skin from UV radiation, photostable UV filters should be used in sunscreen products as much as possible. There are two basic types of UV filters, physical and chemical. The UVB protection factor (SPF) is determined according the COLIPA method, and the UVA protection factor according to the Australian standard.
     
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